Search results for "heterocyclic silyene complexes"

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A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces

2016

The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding.

010405 organic chemistryLigandStereochemistrySilylene010402 general chemistry01 natural sciencesLondon dispersion forcebonding0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryComputational chemistryAmideheterocyclic silyene complexesta116IsopropylDalton Transactions
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A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces

2016

The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding. peerReviewed

heterocyclic silyene complexeskompleksiyhdisteetbonding
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